System and process for injecting catalyst and/or additives into a fluidized catalytic cracking unit

ABSTRACT

Systems for loading catalyst and/or additives into a fluidized catalytic cracking unit are disclosed. Methods of making and using the systems are also disclosed.

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a continuation in part of U.S. applicationSer. No. 12/948,167, filed Nov. 17, 2010 which is a divisional of U.S.application Ser. No. 10/593,499, filed on Sep. 20, 2006, which is thenational phase application of International Patent Application SerialNo. PCT/US2005/009642, filed on Mar. 23, 2005, which is a continuationin part of U.S. application Ser. No. 10/806,563, filed Mar. 23, 2004,the contents of all of which is incorporated by reference herein in itsentirety.

FIELD OF THE INVENTION

The present invention relates to equipment used in fluidized catalyticcracking (FCC) operations and, more particularly, to systems andprocesses for injecting catalyst and/or additives into equipment unitsemployed to conduct FCC operations.

BACKGROUND OF THE INVENTION

FCC units commonly include a circulating inventory of bulk catalyst. Thebulk catalyst is typically used to perform a primary function, such asproducing naptha from petroleum feedstock, the naptha being furtherprocessed into gasoline. Additives, which are often in the samefluidizable and particulated form as the catalyst, are often introducedinto the circulating inventory of bulk catalyst to perform a secondaryfunction such as reducing certain types of emissions, e.g., SOx or NOx,produced by the FCC unit. These emissions are produced in the catalystregenerator of the FCC unit where coke deposits from the crackedpetroleum are burned off and the regenerated catalyst returned to thecirculating catalyst inventory. These additives are usually introducedinto the regenerator using an injection device commonly referred to as a“loader.” Loaders are also used to add catalyst to the bulk inventory asadditional catalyst becomes necessary due to factors such as attritionand deactivation.

Loaders used for catalyst and/or additive injection typically comprise atransfer pot, and a storage hopper or silo located above or proximatethe transfer pot. The catalyst and/or additive is usually transferred tothe storage hopper from a storage bin using a suitable technique such asvacuum transfer. During operation of the loader, a predetermined amountof catalyst and/or additive can be metered to the transfer pot from thestorage hopper. The transfer pot can subsequently be pressurized, andthe catalyst and/or additive can be injected into the regenerator inresponse to the pressure within the transfer pot. This process isusually repeated on a cyclical basis.

The amount of catalyst metered to the transfer pot and injected duringeach cycle is usually small in comparison to the overall volume of thestorage hopper. In other words, a relatively large volume of catalystand/or additive is typically stored in the hopper so that relativelysmall doses of the catalyst and/or additive can be metered to thetransfer pot during each cycle. A typical storage hopper is relativelylarge due to the need to accommodate a large amount of additive orcatalyst therein. For example, a typical storage hopper can have adiameter of five feet or more, and height of fifteen feet or more.

The relatively large size of conventional storage hoppers can limit thenumber of suitable locations in which the loader can be installed. Thischaracteristic can be particularly disadvantageous at a refinery, wherespace can be and often is limited. The need for a relatively large areato accommodate the loader (and in particular the storage hopper) canthus necessitate placing the loader in a less than optimal location.

Moreover, the loader can only be used to inject one type of catalystand/or additive at a time, due to the need for a dedicated storagehopper for each type of catalyst and/or additive. In other words, thetransfer pot can only inject the catalyst and/or additive stored in itsassociated hopper, until the catalyst and/or additive is replaced withanother type of catalyst and/or additive. Hence, loading different typesof catalysts and/or additives on simultaneous or near-simultaneous (backto back) basis can only be accomplished using multiple loaders. Eachadditional loader requires additional outlays of time, labor, and moneyto purchase, install, operate, and maintain. Moreover, each loaderconsumes potentially valuable space within the refinery.

The storage hopper may be pressurized in some applications to facilitatetransfer of the catalyst and/or additive to the transfer pot. Thepressurized air within the hopper can adversely affect the measurementsthat provide an indication of how much catalyst and/or additive has beenadded to the transfer pot. Also, the catalyst and/or additive may beexposed to pressurized air from the refinery (commonly referred to as“plant air”) while it is being transferred to, or stored in the hopper.Plant air often contains moisture or other contaminates that canadversely affect the catalyst and/or additive.

SUMMARY OF THE INVENTION

A preferred embodiment of a system for injecting catalyst and/oradditives into a fluidized catalytic cracking unit comprises a dustcollector in fluid communication with a storage bin holding one of thecatalyst and/or additives, and a vacuum producer in fluid communicationwith the dust collector so that the vacuum producer generates a vacuumwithin the dust collector that draws the one of the catalyst and/oradditives into the dust collector.

The system also comprises a transfer pot for receiving the one of thecatalyst and/or additives from the dust collector. The transfer pot isin fluid communication with the fluidized catalytic cracking unit and asource of pressurized air so that the one of the catalyst and/oradditives is transferred to the fluidized catalytic cracking unit inresponse to a pressure differential between the transfer pot and thefluidized catalytic cracking unit.

A preferred embodiment of a system for loading catalyst and/or additivesinto a fluidized catalytic cracking unit comprises a bin for storing atleast one of the catalyst and/or additives, and a loading unit in fluidcommunication with the storage bin and the fluidized catalytic crackingunit on a selective basis. The loading unit is capable of beingevacuated so that a resulting vacuum within the loading unit draws theat least one of the catalyst and/or additives from the bin, and theloading unit is capable of being pressurized so that the least one ofthe catalyst and/or additives is transferred from the loading unit tothe fluidized catalytic cracking unit.

Another preferred embodiment of a system for loading catalyst and/oradditives into a fluidized catalytic cracking unit comprises a first binfor storing a first of the catalyst and/or additives, a second bin forstoring a second of the catalyst and/or additives, and a loading unit influid communication with the first and second bins and the fluidizedcatalytic cracking unit. The system also comprises a first valve forisolating the first bin from the loading unit on a selective basis, asecond valve for isolating the second bin from the loading unit on aselective basis, and a third valve for isolating the second bin from thefluidized catalytic cracking unit on a selective basis.

A preferred embodiment of a system for introducing catalyst and/oradditives into a fluidized catalytic cracking unit comprises a dustcollecting means in fluid communication with a storage bin holding oneof the catalyst and/or additives, and a vacuum producing means in fluidcommunication with the dust collecting means so that the vacuumproducing means draws the one of the catalyst and/or additives into thedust collecting means. The system also comprises a means for receivingthe one of the catalyst and/or additives from the dust collecting meansand injecting the one of the catalyst and/or additives into thefluidized catalytic cracking unit.

In another preferred embodiment, the system for injecting catalystand/or additives into a fluidized catalytic cracking unit comprises: adust collector in fluid communication with at least one storage binholding one of the catalyst and/or additives; a vacuum producer in fluidcommunication with the dust collector so that the vacuum producergenerates a vacuum within the dust collector that draws the one of thecatalyst and/or additives into the dust collector; a transfer pot influid communication with the dust collector for receiving the one of thecatalyst and/or additives from the dust collector, the transfer potbeing in fluid communication with the fluidized catalytic cracking unitand a source of pressurized air so that the one of the catalyst and/oradditives is transferred to the fluidized catalytic cracking unit inresponse to a pressure differential between the transfer pot and thefluidized catalytic cracking unit; and at least one flexible sectionpositioned between and in fluid communication with the dust collectorand the transfer pot. The at least one flexible section positionedbetween and in fluid communication with the dust collector and thetransfer pot enables the transfer pot and its contents to be weighed,via a plurality of load cells, with little or no weight contributionand/or effect from the dust collector.

In another preferred embodiment, the system for injecting one or morecatalysts and/or additives into a fluidized catalytic cracking unitcomprises: a dust collector in fluid communication with at least onestorage bin holding the one or more catalysts and/or additives; atransfer pot in fluid communication with the dust collector forreceiving the one or more catalysts and/or additives from the dustcollector, the transfer pot being in fluid communication with thefluidized catalytic cracking unit and a source of pressurized air sothat the one or more catalysts and/or additives is transferred to thefluidized catalytic cracking unit in response to a pressure differentialbetween the transfer pot and the fluidized catalytic cracking unit; atleast one flexible section positioned between and in fluid communicationwith the dust collector and the transfer pot; and a plurality of loadcells operatively adapted and positioned to weigh the transfer pot andthe one or more catalysts and/or additives; wherein the at least oneflexible section enables a weight reading of the plurality of load cellsto contain either (i) a minimal weight contribution provided by the dustcollector or (ii) no weight contribution provided by the dust collector.

A preferred process for introducing catalyst and/or additives into afluidized catalytic cracking unit comprises generating a vacuum within aloading unit, drawing one of the catalyst and/or additives from astorage bin and into the loading unit in response to the vacuum,pressurizing the loading unit, and injecting the one of the catalystand/or additives into the fluidized catalytic cracking unit in responseto the pressurization of the loading unit.

A preferred process for loading catalyst and/or additives into afluidized catalytic cracking unit comprises storing at least one of thecatalyst and/or additives at a first location, vacuuming the at leastone of the catalyst and/or additives into a loading unit positioned at asecond location, and injecting the at least one of a catalyst and/oradditives into the fluidized catalytic cracking unit from the loadingunit.

A preferred embodiment of a system for introducing one or moreparticulate substances into a fluid stream comprises a dust collectingmeans in fluid communication with at least one storage bin holding theone or more particulate substances. The system also comprises a vacuumproducing means in fluid communication with the dust collecting means sothat the one or more particulate substances is drawn into the dustcollecting means from the at least one storage bin by a vacuum. Thesystem further comprises a means for receiving the one or moreparticulate substances from the dust collecting means and injecting theone or more particulate substances into the fluid stream.

A preferred conveying process comprises generating a vacuum within adust collector of a loading unit, and drawing a particulate materialfrom a storage bin and into the dust collector in response to the vacuumso that the particulate material enters a transfer pot of the loadingunit adjoining the dust collector. The process also comprisespressurizing the transfer pot, and discharging the particulate materialfrom the transfer pot in response to the pressurization of the transferpot.

In another preferred embodiment, the process for introducing one or morecatalysts and/or additives into a fluidized catalytic cracking unitcomprises: generating a vacuum within a loading unit comprising a dustcollector in fluid communication with and separatable from a transferpot; drawing the one or more catalysts and/or additives from one or morestorage bins and into the dust collector of the loading unit in responseto the vacuum; determining a weight of the one or more catalysts and/oradditives positioned in the transfer pot of the loading unit;pressurizing the transfer pot of the loading unit; and injecting the oneor more catalysts and/or additives into the fluidized catalytic crackingunit in response to reaching a threshold pressure within the transferpot of the loading unit; wherein the determining step comprises weighingthe transfer pot and the one or more catalysts and/or additivespositioned in the transfer pot so as to obtain a transfer pot/contentsweight, wherein the transfer pot/contents weight contains either (i) aminimal weight contribution provided by the dust collector or (ii) noweight contribution provided by the dust collector.

BRIEF DESCRIPTION OF THE DRAWINGS

The foregoing summary, as well as the following detailed description ofa preferred embodiment, are better understood when read in conjunctionwith the appended diagrammatic drawings. For the purpose of illustratingthe invention, the drawings show an embodiment that is presentlypreferred. The invention is not limited, however, to the specificinstrumentalities disclosed in the drawings. In the drawings:

FIG. 1 is a schematic side view of a preferred embodiment of a systemfor injecting catalyst and/or additives into an FCC unit, showing a dustcollector and a transfer pot of the system longitudinal cross section;

FIG. 2 is a diagrammatic side view of the system shown in FIG. 1;

FIG. 3 is a diagrammatic side view of the system shown in FIGS. 1 and 2,from a perspective rotated approximately 180 degrees from theperspective of FIG. 2;

FIG. 4 is a diagrammatic side view of the system shown in FIGS. 1-3,from a perspective rotated approximately 90 degrees from the perspectiveof FIG. 2;

FIG. 5 is a magnified view of the area designated “A” in FIG. 3;

FIG. 6 is a block diagram depicting a control system of the system shownin FIGS. 1-5;

FIG. 7 is a flow diagram depicting operation of the system shown inFIGS. 1-6;

FIG. 8 is a top view of a manifold for use with an alternativeembodiment of the system shown in FIGS. 1-6;

FIG. 9 is a top view of another alternative embodiment of the systemshown in FIGS. 1-6, with a cover of a dust collector of the systemremoved;

FIG. 10 is a top view of another alternative embodiment of the systemshown in FIGS. 1-6, with a cover of a dust collector of the systemremoved;

FIG. 11 is a schematic side view of another preferred embodiment of asystem for injecting catalyst and/or additives into an FCC unit, showinga dust collector and a transfer pot of the system longitudinal crosssection;

FIG. 12 is a schematic side view of yet another preferred embodiment ofa system for injecting catalyst and/or additives into an FCC unit,showing a dust collector and a transfer pot of the system longitudinalcross section; and

FIG. 13 is a cross-sectional view of an exemplary flexible sectionoperatively adapted and sized to be positioned between and connect theexemplary dust collector and the exemplary transfer pot shown in FIGS.11 and 12.

DESCRIPTION OF PREFERRED EMBODIMENTS

A preferred embodiment of a system 10 for injecting one or morecatalysts and/or additives into an FCC unit is depicted in FIGS. 1-6.The loading system 10 forms part of an overall system 11 for storing andloading catalyst and/or additives. The system 11 includes the loadingsystem 10, and one or more storage bins 37.

The loading system 10 comprises a loading unit 14 having a dustcollector 16 and an adjoining transfer pot 18. The loading system 10, asdiscussed in detail below, produces a vacuum that draws catalyst and/oradditive from the storage bins 37 and into the dust collector 16. Thecatalyst and/or additive falls to the bottom of the dust collector 16and into the transfer pot 18. The transfer pot 18 is subsequentlypressurized, and the catalyst and/or additive is injected into aregenerator of the FCC unit in response to the pressure within thetransfer pot 18.

The loading unit 14 can be housed within a cabinet 19 (see FIGS. 2-4).(The cabinet 19 is shown in the figures with its side panels removed,for clarity.) The loading unit 14 is preferably supported by a pluralityof legs 20 affixed to the transfer pot 18.

Cabinet 19 is optional and can be configured to accommodate theparticular configuration and size of the injection system. Preferablyside panels to the cabinet are removable (and/or designed as doors whichare easily opened) and substantially full length and width of theenclosure to give an operator or repair person full access to thesystem. Alternatively, closable portals can be placed in walls that aremore substantially affixed to the system's base, with the portals usedfor access to relatively small components of the system.

The cabinet serves to protect the system from damaging elements in theenvironment, e.g., plant dust, rain, direct sunlight, as well as reducesdusting created by the movement of catalyst as it is drawn in and theninjected by the system. The cabinet also can retain any catalystparticulate that may spill or leak from broken or damaged hoses thattransport catalyst into and throughout the system, as well as retain anyfugitive emissions from the contained equipment.

The cabinet can also be designed to be large enough to provide shelterfor an operator or repair person. The cabinet also “unitizes” thesystem, thereby making it easier to transport and install the system.Indeed, the cabinet could be designed to serve as a shipping containerin addition to serving as a protective enclosure.

The dust collector 16 comprises a sidewall 17. The sidewall 17 should beof a suitable strength and thickness to withstand the presence of avacuum within the dust collector 16.

The cross section and overall shape of the dust collector 16 can vary.The dust collector 16 depicted in the figures has a substantiallycylindrical upper portion 16 a, and a substantially conical lowerportion 16 b that adjoins the upper portion 16 a. An opening 23 isformed in the center of the lower portion 16 b (see FIG. 1). A screen 24is positioned across the lower portion 16 b. In other embodiments, thecross section of the upper portion 16 a and the lower portion 16 b canbe square or rectangular, and the overall shape can be in the form of asquare or rectangular column. (Directional terms such as “upper,”“lower,” etc. are used herein with reference to the componentorientations depicted in FIG. 1. These terms are used for exemplarypurposes only, and are not intended to limit the scope of the appendedclaims.)

The dust collector 16 also includes a cover 25. The cover 25 mates withan upper edge of the sidewall 17. A gasket is positioned between thecover 25 and the sidewall 17 to form a substantially airtight seal therebetween. The sidewall 17 and the cover 25 define an internal volume 26within the dust collector 16 (see FIG. 1).

The dust collector 16 also comprises a suitable filter 32 (see FIG. 1).The filter 32 can be, for example, a Mactiflo model E376094 filter.

The filter 32 is mounted within the upper portion 16 a of the dustcollector 16. The sidewall preferably includes a hatch 33 to provideaccess to the interior of the upper portion 16 a (and the filter 32)(see FIGS. 1 and 4). The hatch 33 is preferably secured the sidewall 17of the dust collector 16 using brackets 34 that permit the hatch 33 tobe removed with a minimal expenditure of time and effort, therebyfacilitating replacement of the filter 32 with a minimum of time andeffort. Alternative embodiments of the loading system 10 can be equippedwith more than one of the filters 32.

The system 10 also comprises suitable vacuum producer 30 (see FIGS. 1and 2). For example, the vacuum producer can be an Empire two-inchVacutran S150 vacuum producer.

The vacuum producer 30 is mounted within the cabinet 19 (see FIG. 2).The vacuum producer 30 is preferably mounted separately from the loadingunit 14. The vacuum producer 30 is in fluid communication with thefilter 32 by way of a hose 35.

The vacuum producer 30 is in fluid communication with a suitable sourceof pressurized air (not shown). (The source of pressurized air can bethe plant air typically available at refineries.) The flow ofpressurized air into the vacuum producer 30 can be regulated by asuitable valve 36 having an actuator 36 a (see FIG. 1).

The vacuum producer 30 can operate in a manner commonly known to thoseskilled in the art of vacuum-chamber design. In particular, opening thevalve 36 permits the pressurized air to flow through the vacuum producer30. The flow of pressurized air through the vacuum producer 30 causesthe vacuum producer 30 to draw air from the internal volume 26 of thedust collector 16, thereby generating a vacuum within the internalvolume 26. (The vacuum producer 30 draws the air through the filter 32,thereby causing the dust collector 16 to collect the dust generated bythe flow of catalyst and/or additive into the dust collector 16.) Therespective directions of various airflows within the loading system 10are denoted by arrows 39 in FIG. 1.

The loading system 10 draws catalyst and/or additive from storage binsin response to the vacuum within the internal volume 26. In particular,the dust collector 16 is in fluid communication with storage bins 37(see FIG. 1). The storage bins 37 hold catalyst and/or additives to beinjected into the FCC unit. The storage bins 37 can be, for example, theshipping containers used to transport the catalyst and/or additives tothe refinery at which the loading system 10 is installed.

Each storage bin 37 is coupled to the dust collector 16 by acorresponding hose (or pipe) 38. A suitable valve 42 having an actuator42 a is located between each hose 38 and the dust collector 16. Eachvalve 42 isolates its associated storage bin 37 from the dust collector16 on a selective basis. The valves 42 are installed on the upperportion 16 a of the dust collector 16, and are in fluid communicationwith the internal volume 26 by way of corresponding openings formed inthe upper portion 16 a of the dust collector 16. (The hoses 38 andvalves 42 thus form part of the system 11 for storing and loadingcatalyst and/or additives).

The hoses 38 can be coupled to the upper portion 16 a by way of a commonmanifold 74 in alternative embodiments, as shown in FIG. 8.

The hoses 38 are preferably equipped with fittings that permit the hoses38 to be readily removed from the dust collector 16 (or the manifold 74)and the storage bins 37.

Opening one of the valves 42 permits catalyst and/or additive to bedrawn from the associated storage bin 37 by way of the associated hose38, in response to the vacuum within the internal volume 26. Thecatalyst and/or additive is thus drawn directly from one of storage bins37 and into the loading system 10, without a need to load the catalystand/or additive into a storage hopper.

The loading system 10 is depicted as being equipped with three sets ofthe valves 42 and hoses 38, for exemplary purposes only. Alternativeembodiments can be equipped with more or less than three valves 42 andthree hoses 38, and can draw catalyst and/or additive from more or lessthan three of the storage bins 37.

One or more (2, 3, 4, etc.) storage bins 37 can be positioned at alocation remote from the loading system 10. For example, the storagebins 37 can be located up to twenty feet from the loading system 10.(The maximum distance between the loading system 10 and the storage bins37 is application dependent, and can vary with factors such as thecapacity of the vacuum producer 30, the diameter of the hoses 38, etc. Aparticular value for this parameter is specified for exemplary purposesonly.)

As shown in FIG. 1, the dust collector 16 includes three pipe guides 40.Each pipe guide 40 is in fluid communication with an associated one ofthe hoses 38.

The catalyst and/or additive drawn into the internal volume 26 by way ofone of the pipe guides 40. The pipe guides 40 discharge the catalyst oradditive proximate into the internal volume 26, proximate the screen 24.

Alternative configurations of manifold 74 include an internal manifold,such as the manifold 100 depicted in FIG. 9. In such an embodiment, oneor more individual hoses 38 can be routed through portals in the upperportion 16 a, with the portals preferably sealed via gaskets or thelike. One or more pipe guides 102 can be secured to the sidewalls of theupper portion 16 a by a suitable means such as welds, flanges, brackets,fasteners, etc., so that the pipe guides 102 extend into the upperportion 16 a.

Each of the hoses 38 are then coupled by way of the common manifold 100that is located inside the upper portion 16 a. The manifold 100 caninclude valves, such as the valves 42, for placing the manifold 100 (andthe dust collector 16) in fluid communication with the associated hose38 and storage bin 37 on a selective basis. A single discharge pipeguide 104 (as opposed to the multiple pipe guides 40 illustrated inFIG. 1) can descend from the manifold 100 in the direction of the bottomportion of 16 b. The end of the discharge pipe guide 104 preferably islocated approximately six inches above the opening 23 formed in thelower portion 16 b of the dust collector 16. (The optimal distancebetween the end of the discharge pipe guide 104 and the opening 23 canvary by application; a specific value for this distance is presented forexemplary purposes only.) This configuration of hoses 38, manifold 100,and single discharge pipe guide 104 create a “spider” arrangement ofhoses such that the single discharge pipe guide 104 can be positioned inthe center of the upper portion 16 a. Centering the manifold 100 and theassociated discharge pipe guide 104 insures that catalyst and/oradditive is deposited at the bottom of dust collector 16. Thisconfiguration helps reduce catalyst and/or additive striking the sidesof the upper portion 16 a, and thereby reduces any potential build up ofcatalyst and/or additive on those walls. This configuration alsopotentially reduces catalyst and/or additive attrition that could occuras the catalyst and/or additive particulate strikes the sidewalls.

Another arrangement for discharging the catalyst and/or additive intothe dust collector 16 is depicted in FIG. 10. In this embodiment, one ormore of the individual hoses 38 can be routed through portals in theupper portion 16 a, with the portals preferably sealed via gaskets orthe like. One or more pipe guides 110 can be secured to the sidewall ofthe upper portion 16 a by a suitable means such as welds, flanges,brackets, fasteners, etc., so that each pipe guide 110 receives catalystand/or additive from a respective hose 38. A valve, such as the valve42, can be mounted on each pipe guide 110 to place the pipe guide 110(and the dust collector 16) in fluid communication with the associatedhose 38 and storage bin 37 on a selective basis. Each valve 42 can bemounted on the sidewall of the upper portion 16 a by a suitable meanssuch as flanges.

The pipe guides 110 each extend inward from the sidewall of the upperportion 16 a, so that the respective ends of the pipe guides 110 arelocated proximate the centerline of the dust collector 16. The ends ofthe pipe guides 110 can be secured to each other by a suitable meanssuch as welding, fasteners, brackets, etc. Each pipe guide 110 thusdischarges catalyst and/or additive proximate the centerline of the dustcollector 16. The pipe guides 110 preferably extend downward, at anangle of approximately seventy degrees in relation to the horizontaldirection. (The optimal orientation of the pipe guides 110 can vary byapplication; a specific orientation is presented for exemplary purposesonly.) The ends of the pipe guides 100 preferably are locatedapproximately six inches above the opening 23 formed in the lowerportion 16 b of the dust collector 16. (The optimal distance between theends of the pipe guides 110 and the opening 23 can vary by application;a specific value for this distance is presented for exemplary purposesonly.) This configuration helps reduce catalyst and/or additive strikingthe sides of the upper portion 16 a, and thereby reduces any potentialbuild up of catalyst and/or additive on those walls. This configurationalso potentially reduces catalyst and/or additive attrition that couldoccur as the catalyst and/or additive particulate strikes the sidewalls.

It should be noted that the depiction of the system 11 in FIG. 1 isschematic in nature, and the relative positions of the various hoses,piping, etc. of the system 11 can be different than those depicted inFIG. 1. For example, the openings formed in the upper portion 16 a ofthe dust collector 16 to accommodate the hoses 38 can be positionedaround the circumference of the upper portion 16 a, in lieu of thevertical arrangement depicted in FIG. 1. In other embodiments, multiplehoses can be positioned on two or more sides of upper portion 16 a.

The catalyst or additive drops toward the bottom of the dust collector16, i.e., toward the lower portion 16 b, after being discharged from thepipe guides 40 (or the discharge pipe guide 104 or pipe guides 110) dueto gravity. The catalyst and/or additive passes through the screen 24 asit drops (see FIG. 1). The mesh of the screen 24 is preferably chosen toblock the passage of relatively large clumps or catalyst and/or additive(or foreign objects), while permitting relatively fine granules ofcatalyst and/or additive to flow freely there through. The substantiallyconical shape of the lower portion 16 b directs the catalyst and/oradditive toward the opening 23 in the lower portion 16 b.

The loading system 10 includes the valve 43 for covering and sealing theopening 23 on a selective basis. The valve 43 can be, for example, aplug valve comprising a seat 44 and plug 45. The seat 44 is secured tothe lower portion 16 b, around the periphery of the opening 23. The plug45 is movable between an upper and a lower position (the plug 45 isdepicted in its lower position in FIG. 1).

The valve 43 is actuated by pressurized air. The pressurized air isdirected to the valve 43 by way of piping 46 that extends through thetransfer pot 18. The flow of pressurized air into the piping 46 can beinitiated and interrupted on a selective basis by a valve 48 in fluidcommunication with the piping 46. The valve 48 a includes an actuator 48a.

The pressurized air impinges upon the plug 45 after exiting of thepiping 46. More particularly, the pressurized air is directed to theinterior of the plug 45, and urges the plug 45 into its closed positionagainst the seat 44. The contact between the plug 45 and the seat 44substantially seals the opening 23.

The plug 45 drops from its closed to its open position when thepressurized air is interrupted by closing the valve 48. The resultinggap between the plug 45 and the seat 44 permits catalyst and/or additivereaching the bottom of the lower portion 16 b to pass through theopening 23 and into the transfer pot 18 (see FIG. 1).

The loading system 10 preferably includes a volume chamber and moisturetrap 49 in fluid communication with the piping 46 (see FIGS. 1 and 2).The volume chamber and moisture trap 49 removes moisture from thepressurized air directed to the valve 43.

The transfer pot 18 comprises a sidewall 51. The sidewall 51 should beof a suitable strength and thickness to withstand pressurization of thetransfer pot 18.

The cross section and overall shape of the transfer pot 18 can vary. Thetransfer pot 18 depicted in the figures has a substantially cylindricalupper portion 18 a, and a substantially conical lower portion 18 b thatadjoins the upper portion 18 a. The upper portion 18 a and the lowerportion 18 b of the transfer pot 18, and the lower portion 16 b of thedust collector 16 define an internal volume 50 within the transfer pot18 (see FIG. 1). (The lower portion 16 b and the valve 43 thus form aboundary between the internal volume 26 of the dust collector 16 and theinternal volume 50 of the transfer pot 18.)

An opening 53 is formed in the center of the lower portion 18 a of thetransfer pot 18. The transfer pot 18 is coupled to the regenerator ofthe FCC unit by piping 54. The piping 54 is in fluid communication withthe opening 53. Catalyst and/or additive enters the piping 54 by way ofthe opening 53 and subsequently flows to the regenerator, as discussedbelow.

A valve 55 having an actuator 55 a is installed in piping 54. The valve55 permits the transfer pot 18 to be isolated from the regenerator on aselective basis. A suitable transfer pot 18 can be obtained, forexample, by adapting a Clemtex, Inc. model 2452 six-cubic footsandblasting pot, or a model 1648 two-cubic-foot sandblasting pot tomate with the dust collector 16. (The sandblasting pot can be mated withthe dust collector 16 by securing the lower portion 16 b of the dustcollector 16 to the upper periphery of the sandblasting pot by asuitable means such as welding.)

The loading unit 14 is supported by a plurality of load cells 56 (seeFIGS. 1 and 4). The load cells 56, as discussed below, provide a measureof the weight of the loading unit 14 in both an unloaded and loadedcondition, i.e., with and without catalyst and/or additive therein. Theload cells 56 are preferably mounted between a base 19 a of the cabinet19, and a plate 57 fixedly coupled to the legs 20 of the transfer pot18.

Each load cell can be restrained from substantial horizontal movement bya corresponding restraint 61 (the restraints 61 are shown only in FIG.5, for clarity.) Each restraint 51 is pivotally coupled to the base 19 aof the cabinet 19.

The loading system 10 can include a plurality of jack assemblies 62 (thejack assemblies 62 are shown only in FIG. 5, for clarity.) Each jackassembly 62 comprises a threaded shaft 62 a fixedly coupled to the base19 a of the cabinet 19. Two nuts 62 b are threadably coupled to eachshaft 62 a. The nuts 62 b are located above and below the plate 57. Thelower nuts 62 b can be raised so that the lower nuts 62 b support theplate 57 (and the portion of the loading system 10 positioned on theplate 57). The upper nuts 62 b can be lowered to lock the plate 57 inposition, i.e., the plate 57 can be sandwiched between the upper andlower nuts 62 b.

The jack assemblies 62 can thus substantially isolate the load cells 57from the weight of the loading system 10. This feature can be used, forexample, to protect the load cells 57 from being damaged by impact loadsduring shipping of the loading system 10.

External connections to the loading unit 14 are preferably configured soas to introduce a negligible tare into the load cell readings. Forexample, the piping 54 includes a flexible sections 54 a thatsubstantially decouples the transfer pot 18 from the portion of thepiping 54 connected to the regenerator, thereby minimizing any tareintroduced into the load cell readings (see FIG. 1). The piping 46likewise includes a flexible section 46 a that substantially decouplesthe transfer pot 18 from the portion of the piping 46 connected to theplant-air equipment. Moreover, the hoses 35, 38 preferably havesufficient flexibility so that any tare introduced thereby isnegligible.

The internal volume 26 of the dust collector 16 and the internal volume50 of the transfer pot 18 are in fluid communication on a selectivebasis by way of piping 58. A valve 59 having an actuator 59 a is locatedin the piping 58 to selectively open and close the path formed by thepiping 58. The piping 58 is used to equalize the pressures within theinternal volumes 26, 50, as discussed below.

The loading system 10 preferably comprises a controller 60 (see FIGS. 3and 6). The actuators 36 a, 42 a, 48 a, 55 a, 59 a of the respectivevalves 36, 42, 48, 55, 59 are electrically coupled to the controller 60.This feature permits the operation of the valves 36, 42, 48, 55, 59 tobe controlled by the controller 60.

The controller 60 is a programmable loop controller (PLC), althoughvirtually any type of computing device such as a minicomputer,microcomputer, etc. can be used as the controller 60 in alternativeembodiments. A server or mainframe computer that controls otherequipment and processes at the refinery in which the loading system 10is operated can also be used to control the loading system 10 in thealternative. For example, a computer based system known as a“distributed control system” or DCS is an example of a centralizedsystem used by FCC unit operators to control a number of unitoperations. Controller 60 can be coupled to and/or communications linescan be established between controller 60 and the DCS so that the DCScontrols the loading system through the controller.

The controller 60 can include a control panel 64 for inputting commandsand operating data to the controller 60 (see FIGS. 3 and 6). Thecontroller 60 and the control panel 64 can be mounted on the cabinet 19.The control panel 64 by itself, or both the control panel 64 and thecontroller 60 can be mounted at a convenient location remote from theremainder of the loading system 10 in alternative embodiments. Forexample, the control panel 64 can be mounted in a central control roomof the refinery, thus allowing the operation of the loading system 10 tobe controlled on a remote basis.

The controller 60 can be configured to cause a predetermined amount ofcatalyst and/or additive to be injected into the regenerator. Thepredetermined amount can be input to the controller 60 by the user viathe control panel 64.

Moreover, the controller 60 can be configured to facilitate injection ofthe catalyst and/or additive on a cyclical basis. For example, thecontroller 60 can be programmed to facilitate the injection of apredetermined amount of additive over a twenty-four hour period, i.e.,per day, using a predetermined number of discrete injections over thatperiod. The operation of the loading system 10 over one such cycle isdescribed below, and is depicted in the form of a flow diagram in FIG.7.

(The controller 60 can also be configured to facilitate injection of thecatalyst and/or additive on a non-cyclical basis. In other words, thecontroller 60 can be programmed to facilitate periodic injections ofvarying amounts of catalyst and/or additive.)

The total amount of catalyst and/or additive to be injected over thetwenty-four hour period can be input to the controller 60 by the userusing the control panel 64. The number of discrete injections to beperformed per day can also be input by way of the control panel 64. (Thecontroller 60 can be programmed to operate based on other inputs inalternative embodiments. For example, the controller 60 can beprogrammed to inject a predetermined amount of additive per cycle, usingpredetermined interval between injections.)

The controller 60 can be programmed to automatically calculate theamount of catalyst and/or additive to be injected during each cyclebased on the above-noted inputs. The controller 60 can also beprogrammed to calculate the time interval between the start of eachinjection. The interval is calculated by dividing twenty-four hours bythe required number of injections per day. Moreover, the controller 60can be configured to accept an input denoting the particular storage bin37 from which the catalyst and/or additive is to be drawn.

The controller 60 sends a control input to the actuator 42 a of thevalve 42 associated with the particular storage bin 37 from which thecatalyst and/or additive is to be drawn (see FIG. 7). The control inputcauses the actuator 42 a to open the valve 42, thereby placing thestorage bin 37 in fluid communication with the dust collector 16. (Thevalves 36, 42, 48, 55, 59 are in their respective closed positions, andthe plug 45 of the valve 43 is in its open (lower) position at the startof the cycle.)

The controller 60 also sends an input to the actuator 36 a of the valve36, thereby allowing pressurized air to flow through the vacuum producer30. The vacuum producer 30 creates a vacuum within the internal volume26 of the dust collector 16 in response to the flow of pressurized airtherethrough, as discussed above.

The vacuum within the internal volume 26 draws the catalyst and/oradditive from the storage bin 37 and into the upper portion 16 a of thedust collector 16. (The direction of travel of the catalyst and/oradditive through the loading system 10 is denoted by arrows 65 in FIG.1.) The catalyst and/or additive subsequently falls toward the lowerportion 16 b due to gravity, and enters the transfer pot 18 by way ofthe opening 23 in the lower portion 16 b, as noted previously.

The controller 60 continually monitors the weight of the loading unit14, and the weight of the catalyst and/or additive added thereto. (Thecombined weight of the loading unit 14 and any catalyst and/or additivetherein is hereinafter referred to as the “live weight” of the loadingsystem 10). In particular, the load cells 56 are electrically coupled tothe controller 60. The controller 60 receives inputs from each of theload cells 56, and adds the inputs to determine the live weight of theloading system 10.

The controller 60 calculates the amount of catalyst and/or additive thatis added to the loading system 10. The controller 60 performs thiscalculation by subtracting the live weight of the loading system 10 at agiven instant from the live weight of the loading system 10 at the startof the cycle, i.e., immediately prior to the opening of the valves 36,42 (the loading unit 14 is assumed to be substantially empty of catalystand/or additive at the start of the cycle).

The controller 60 stops the flow of catalyst and/or additive to the dustcollector 16 as the amount of catalyst and/or additive added to theloading system 10 approaches the amount to be injected into theregenerator during each cycle (this amount is subsequently referred toas a “target value”). In particular, the controller 60 sends a controlinput to the actuator 42 a of the open the valve 42 as the weight of thecatalyst of additive approaches its target value. The control inputcauses the valve 42 to close, thereby interrupting the flow of catalystand/or additive to the dust collector 16. (The controller 60 can beprogrammed to commence the closing of the valve 42 when the weight ofthe catalyst and/or additive is below the target weight by apredetermined amount, so as to compensate for the lag between theissuance of the “close” command to the valve 42, and the point at whichthe valve 42 is fully closed).

The controller 60 also sends a control input to the actuator 36 a of thevalve 36 as the weight of the catalyst of additive in the loading system10 reaches its target value. The control input causes the actuator 36 ato close the valve 36, thereby interrupting the flow of pressurized airthrough the vacuum producer 30.

The controller 60 subsequently sends a control input to the actuator 48a of the valve 48 to cause the valve 48 to open. Opening the valve 48permits pressurized air to enter the internal volume 50 of the transferpot by way of the piping 46. The pressurized air impinges on the plug 45of the valve 43 upon exiting the piping 46, and thereby urges the plug45 into its closed (upper) position against the lower portion 16 b ofthe dust collector 16, as discussed above. The contact between the plug45 and the lower portion 16 b covers and seals the opening 23.

The pressurized air pressurizes the internal volume 50 of the transferpot 18 after the opening 23 has been sealed by the plug 45. (Thepressurized air, as discussed above, is dried by the volume chamber andmoisture trap 49 before reaching the transfer pot 18, thereby minimizingthe potential for contamination of the catalyst and/or additive withinthe transfer pot 18.)

The controller 60 receives an input from a first pressure transducer 68that measures the pneumatic pressure in the internal volume 50 (see FIG.6). The controller 60 also receives an input from a second pressuretransducer 70 that measures the pneumatic pressure in the regeneratorproximate the location at which the catalyst and/or additive isinjected.

The controller 60 sends a control input to the actuator 48 a of thevalve 48 when the difference between the pneumatic pressures in theinternal volume 50 and the regenerator 14 reaches a predetermined value,i.e., when the pressure in the internal volume 50 exceeds the pressurein the regenerator by a predetermined amount. This control input causesthe valve 48 to close.

The controller 60 subsequently sends a control input to the actuator 55a of the valve 55 to cause the valve 55 to open. The differentialbetween the pressures in the internal volume 50 and the regeneratorcauses the catalyst and/or additive in the transfer pot 18 to flow intothe regenerator by way of the piping 54.

The controller 60 sends a control input to the actuator 55 a to closethe valve 55, after a predetermined interval has passed followingissuance of the control input to open the valve 55. (The predeterminedinterval should be chosen so as to allow sufficient time forsubstantially all of the catalyst and/or additive in the transfer pot 18to be injected into the regenerator). Alternatively, the controller 60can send a control input to the actuator 55 a to close the valve 55 whenthe pressure differential between the internal volume 50 and theregenerator reaches approximately zero.

The controller 60 subsequently sends a control input to the actuator 59a of the valve 59 to cause the valve 59 to open. The opening of thevalve 59 permits the pneumatic pressures within the internal volumes 26,50 to substantially equalize. In particular, opening the valve 59relieves the relatively high pressure in the internal volume 50 (whichis approximately equal to pressure within the regenerator 14) by way ofthe piping 58.

The controller 60 sends a control input to the actuator 59 a of thevalve 59 when the pressure differential between the internal volumes 26,50 is approximately zero (the pneumatic pressure in the internal volume26 can be measured by a third pressure transducer 72 located therein).This control input causes the valve 59 to close.

The controller 60 can be programmed to repeat the above process afterthe calculated interval between the start of each injection cycle(discussed above) has passed.

Moreover, the controller 60 can be programmed to inject catalyst and/oradditive from any of the other storage bins 37 after the above-describedcycle has been completed. In other words, another injection cycle can beperformed in a manner identical to that described above, with theexception that the valve 42 associated with one of the other storagebins 37 can be opened to allow the catalyst and/or additive from thatparticular storage bin 37 to be drawn into the dust collector 16.

Vacuuming the catalyst and/or additive directly from its storage bin 37can provide substantial flexibility in the operation of the loadingsystem 10. For example, the loading system 10 can draw catalyst and/oradditive from virtually any location at the refinery accessible by ahose such as the hose 38. Hence, the storage bins 37 can be positionedat an optimal location within the refinery. Moreover, the use of vacuumas a means to transport the catalyst and/or additive to the loadingsystem 10 can permit the catalyst and/or additive to be drawn directlyfrom its shipping container. Hence, the expenditure of time and laborassociated with transferring the catalyst and/or additive from itsshipping container to a storage unit can be eliminated through the useof the loading system 10.

Moreover, vacuuming the catalyst and/or additive directly into the dustcollector 16 can obviate the need to transfer the catalyst and/oradditive into a relatively large storage hopper (as is typicallyrequired with conventional loaders). Hence, the expenditure of time andlabor associated with transferring the catalyst and/or additive to astorage hopper can be eliminated through the use of the loading system10.

Eliminating the need for a storage hopper can also minimize the amountof space needed to accommodate the loading system 10. For example, thefootprint the loading system 10 is approximately four feet by four feet,and the maximum height of the loading system is approximately five feet.A conventional loader of comparable capacity (with its storage hopper)can have a footprint of approximately five feet by eight feet, and aheight of approximately twenty feet. (The dimensions of the loadingsystem 10 will vary by application, and specific dimensions are providedherein for exemplary purposes only.) Moreover, in contradistinction tomany conventional loaders, the loading system 10 can be installedwithout the use of special mounting provisions such as a basespecifically tailored to a particular installation.

The loading system 10 can be repositioned with relative ease due to theabsence of a storage hopper. In particular, the absence of a storagehopper provides a measure of portability to the loading system 10, andcan facilitate movement of the loading system 10 between differentlocations within the refinery (or between different refineries) with aminimal expenditure of time and effort in comparison to conventionalloaders. Portability and ease of use for the user of the loading system10 is further enhanced when the loading system 10 is used in conjunctionwith portable storage bins, e.g., known as “totes,” which are normallybuilt to hold approximately 2,000 pounds (approximately 900 kilograms)of catalyst and/or additive.

The absence of a storage hopper, it is believed, can also minimize theamount of time necessary to install the loading system 10 in relation toconventional loaders. The ability to install the loading system 10 in aminimal amount of time can be particularly beneficial, for example,where the use of the loading system 10 is required on an immediate basisto comply with a particular regulatory standard.

The loading system 10 can be used to inject different types of catalystand/or additives with no mechanical reconfiguration, and without theneed to unload and reload a storage hopper. In particular, the loadingsystem 10 can inject one type of catalyst and/or additive from one ofthe storage bins 37, and can immediately thereafter inject another typeof catalyst from another of the storage bins 37 by manipulating thevalves 42 in the appropriate manner. Of course, the loading system 10can also be used to load product stored in just one storage bin. In anyevent, the need for multiple loaders to inject different types ofcatalyst and/or additives can thus be eliminated through the use of theloading system 10. It is believed that that substantial savings in time,labor, refinery space, and money can be achieved by eliminating the needto purchase, install, and maintain multiple loaders each dedicated to aparticular type of catalyst and/or additive.

Eliminating multiple loaders and employing the invention also eliminatesmultiple lines from the loaders being connected to the catalyst and/oradditive addition line of the FCC unit, and in particular the catalystand/or additive addition line to the FCC unit's regenerator. Havingmultiple lines routed into the catalyst and/or additive addition linecan lead to blockages at the point where the multiple lines converge, orcauses blockages close thereto. Typical embodiments of the invention,however, are designed to have only one supply line exiting the loadingsystem and to be connected to the catalyst and/or additive addition lineof the FCC unit, and therefore do not provide a routing configurationthat leads to the aforementioned blockages.

Eliminating the use of a storage hopper can also reduce the amount ofmoisture to which the catalyst and/or additive is exposed. Inparticular, the use of the loading system 10 permits the catalyst and/oradditive to remain in the storage bins 37 until a point immediatelyprior to its injection into the regenerator 14. The environment in thestorage bins 37, it is believed, can be controlled more closely thanthat within a storage hopper. In particular, catalyst and/or additive istypically exposed to plant air when being transported to and stored in ahopper. Plant air is often a source of moisture, oil based products, orother contamination that can adversely affect catalyst and/or additive.Hence, minimizing the exposure of the catalyst and/or additive to plantair, as in the loading system 10, can reduce the potential forcontamination of the catalyst and/or additive. Reducing suchcontamination also reduces the catalyst and/or additive fromagglomerating or clumping together. Such agglomeration makes thecatalyst and/or additive less fluid, and can lead to plugging of hosesand supply lines. The invention thereby helps insure that the catalystremains fluid as it is transported through the system.

As a result of the invention reducing contamination and inadvertentwater absorption, the invention can be employed to load and/or transporthygroscopic material wherein it is desirable to process, handle anddeliver such material with little increase in water uptake. By“hygroscopic”, it is meant having the property of absorbing atmosphericmoisture. Hygroscopic materials include, but are not limited to, foodproducts, pharmaceuticals and industrial chemicals, as well as catalystand/or additives, e.g., FCC catalysts and/or additives. The invention isalso suitable for delivering materials that are formulated or otherwisepossess pyrophoric properties when used, e.g., spark or flame inducing.

For the purpose of understanding such uses, one can refer to earlierdescriptions relating to delivering catalyst and/or additive and applythose teachings when using the invention to store, process, handleand/or deliver hygroscopic or pyrophoric material. For example, it isenvisioned that the invention be can used to transport and/or deliverhygroscopic material and pyrophoric material to delivery vehicles,reactor units, mixers, or storage containers designed for delivery ofthe materials to individual consumers of the relevant product.

The pressurized volume loading system 10 is believed to be less thanthat of conventional loaders of comparable capacity. Hence, lesspressurized air is required to operate the loading system 10 incomparison to conventional loaders. This feature can reduce theoperating cost of the loading system 10 in relation to conventionalloaders. For example, in instances where multiple conventional loadersare employed in a plant, consumption of pressurized plant air can besignificant, especially when multiple conventional loaders are beingoperated simultaneously. Indeed, there can be large pressure drops whensimultaneously using multiple loaders of the conventional type. Suchpressure drops can lead to incomplete delivery of catalyst and/oradditive, as well detrimentally affect the performance of other plantoperations that employ plant air. These pressure drops, however, can beavoided when using typical embodiments of the invention.

The loading unit 14 is substantially isolated from sources ofpressurized air as the catalyst and/or additive is transferred thereto,due primarily to the use of a vacuum to transfer the catalyst and/oradditive. Hence, the potential for the readings of the load cells 56 tobe biased by forces induced by pressurized air is believed to beminimal. (Some types of conventional loaders, as discussed above,transfer catalyst and/or additive under pressure from a storage hopperto a transport unit. The pressurized air used to affect the transfer canadversely affect readings of the transfer pot's weight.)

Further embodiments of the present invention, shown in FIGS. 11-13, arebelieved to further minimize one or more system variables that canpotentially negatively impact a measured weight of the transfer pot andthe one or more catalysts and/or additives contained therein as measuredby the load cells 56. In these systems, at least one flexible section ispositioned between and is in fluid communication with (i) the dustcollector and (ii) the transfer pot so as to separate the dust collectorfrom the transfer pot in such a manner so that the weight of the dustcollector has little, if any, effect on a weight measurement of thetransfer pot and its contents as measured by a plurality of load cells.

In particular, in the systems shown in FIGS. 11-12, the weightmeasurement of the transfer pot and its contents, as measured by aplurality of load cells, contains either (i) a minimal weightcontribution provided by the dust collector or (ii) no weightcontribution at all provided by the dust collector. As used herein, thephrase “a minimal weight contribution provided by the dust collector”refers to a weight contribution of the dust collector to the weightmeasurement (i.e., the weight measurement of the transfer pot and itscontents as measured by the plurality of load cells) of greater thanzero grams (g) and less than about 100 g (desirably, less than about 50g, more desirably, less than about 25 g). As used herein, the phrase “noweight contribution provided by the dust collector” refers to a weightcontribution of the dust collector to the weight measurement (i.e., theweight measurement of the transfer pot and its contents as measured bythe plurality of load cells) equal to zero grams.

As shown in FIG. 11, overall system 110 comprises many of the componentsof overall system 11, as well as some additional system features.Overall system 110 comprises loading system 100, wherein the dustcollector 160 and the transfer pot 180 are separated from one another bydust collector flange 168 forming an outlet for dust collector 160 andtransfer pot flange 368 forming an inlet for transfer pot 180. Flexiblesection 168 a bridges a space positioned therebetween dust collectorflange 168 and transfer pot flange 368. Flexible section 168 asubstantially decouples the dust collector 160 from the transfer pot180, thereby minimizing (i.e., desirably, completely eliminating) anytare weight contributed by the dust collector 160, the contents of thedust collector 160 (e.g., filter 32, pipe guides 40, particles that donot pass thru screen 24, etc.), and the components attached to the dustcollector 160 (e.g., hoses 35 and 38, valves 42, dust collector flange168, etc.) into the weight measurements of the plurality of load cells56 (see FIG. 11).

As shown in FIG. 11, piping 58 may also comprise a flexible section 58a, which further decouples the dust collector 160 from the transfer pot180, thereby further minimizing (i.e., desirably, completelyeliminating) any tare weight contributed by the dust collector 160, thecontents of the dust collector 160, and the components attached to thedust collector 160 into weight measurements of the plurality of loadcells 56 (see FIG. 11).

Loading system 100 further comprises legs 120, which support the weightof the dust collector 160 above the transfer pot 180. In alternativeembodiments (not shown), the weight of the dust collector 160 may besupported by wall structure of the cabinet 19 (see, the cabinet 19 inFIGS. 2-4).

Loading system 100 operates in a manner as described above in referenceto loading system 10, except that load cells 56 only weigh the transferpot 180, its contents (i.e., the catalyst and/or additive), and anycomponents directly attached to the transfer pot 180 (i.e., a portion ofpiping 46, plug 45, transfer pot flange 368, a portion of piping 58, aportion of piping 54, valve 59, and legs 20 as shown in FIG. 11). Inthis embodiment, the plurality of load cells 56 do not weigh the dustcollector 160, the contents of the dust collector 160 (e.g., filter 32,pipe guides 40, particles that do not pass thru screen 24), and thecomponents attached to the dust collector 160. As discussed above, theweight measurement of the transfer pot 180 and its contents (i.e., thecatalyst and/or additive), as measured by the plurality of load cells56, contains either (i) a minimal weight contribution provided by thedust collector 160 (as well as the contents of the dust collector 160(e.g., filter 32, pipe guides 40, particles that do not pass thru screen24), and the components attached to the dust collector 160) or (ii) noweight contribution at all provided by the dust collector 160 (as wellas the contents of the dust collector 160 (e.g., filter 32, pipe guides40, particles that do not pass thru screen 24), and the componentsattached to the dust collector 160).

As shown in FIG. 11, piping 46 extends into a sidewall 51 of thetransfer pot 180 so as to supply air pressure onto plug 45 to enable (1)closing/sealing of the transfer pot 180 at seat 144, and (2)pressurizing of the transfer pot 180 for transfer of one or morecatalysts and/or additives from the transfer pot 180 to the fluidizedcatalytic cracking unit (not shown) via piping 54. FIG. 11 also depictspiping 58 extending out of a sidewall 51 of the transfer pot 180 so asto provide an air exit for (1) depressurizing the transfer pot 180, and(2) equalizing the pressure between the transfer pot 180 and the dustcollector 160.

Although not shown in FIG. 11, transfer pot 180 may further comprise oneor more additional components. In one exemplary embodiment (not shown),transfer pot 180 may further comprise (i) a lid component with transferpot flange 368 separately fastened, or integrally connected, to andextending above, through and below the lid component, (ii) an internalflange portion extending below the lid component and into transfer pot180 (i.e., in parallel alignment with transfer pot flange 368, anddesirably, integrally connected with transfer pot flange 368 so as toform an extension of transfer pot flange 368 below the lid component),and (iii) an internal upper wall within transfer pot 180, wherein apressurized volume within transfer pot 180 is bound by (1) one or morevertically-extending side walls and (2) the internal upper wall withintransfer pot 180. In one configuration, the internal upper wall has aconcave cross section as it projects into the transfer pot, e.g., toimpart optimal pressurization properties. In this embodiment, theinternal upper wall within transfer pot 180 has an opening therethroughfor housing/supporting a distal flange end of the internal flangeportion extending below the lid component and into transfer pot 180 adesired distance above plug 45 shown in FIG. 11. The internal flange mayfurther comprise a flange end configuration and/or component (e.g., arubber “O” ring) that provides a plug seat for plug 45 (i.e., the flangeend has dimensions and a shape, and optionally an “O” ring, that matchesthe dimensions and shape of plug 45 so as to provide a seal).

As shown in FIG. 11, the dust collector 160 includes three pipe guides40, wherein each pipe guide 40 is in fluid communication with anassociated one of the hoses 38, similar to loading system 10 shown inFIG. 1. Catalyst and/or additive is drawn into the internal volume 26 ofdust collector 216 by way of one of the pipe guides 40, and isdischarged proximate screen 24 as shown in FIG. 11. Similar to loadingsystem 10 shown in FIG. 1, alternative manifold and guide pipesillustrated in FIGS. 8-10 may be used within loading system 110 shown inFIG. 11.

FIG. 12 depicts another exemplary loading system of the presentinvention. As shown in FIG. 12, overall system 211 comprises similarcomponents as described within overall system 110. Similar to overallsystem 110, overall system 211 comprises loading system 210, wherein thedust collector 216 and the transfer pot 218 are separated from oneanother by dust collector flange 268 forming an outlet for dustcollector 216 and transfer pot flange 368 forming an inlet into transferpot 218. Flexible section 268 a bridges a space positioned therebetweendust collector flange 268 and transfer pot flange 368. Flexible section268 a substantially decouples the dust collector 216 from the transferpot 218, thereby minimizing (i.e., desirably, completely eliminating)any tare weight contributed by the dust collector 216, contents of thedust collector 216 (e.g., filter 32, pipe guide 40, particles that donot pass thru screen 24, etc.), components attached to the dustcollector 216 (e.g., hoses 35 and 38, valves 42, manifold 74, dustcollector flange 268, portions of piping 46 and 58, etc.) and componentsattached to or contained within dust collector flange 268 (e.g., portionof hoses 46 and 58, and plug 45) into weight measurements of the loadcells 56 (see FIG. 12) (or results in a minimal weight contribution ofthe dust collector 216 into any weight measurement of the plurality ofload cells 56 as discussed above).

As shown in FIG. 12, the transfer pot 218 does not have any pipingentering or exiting the transfer pot 218 other than inlet transfer potflange 368 and outlet piping 54. In this embodiment, piping 46 extendsinto a side wall 268 c of dust collector flange 268 extending from dustcollector 216 so as to supply air pressure onto plug 45, also positionedwithin dust collector flange 268, to enable (1) closing/sealing of thedust collector 216 at seat 44, and (2) pressurizing of the transfer pot218 for transfer of one or more catalysts and/or additives from thetransfer pot 218 to the fluidized catalytic cracking unit (not shown)via outlet piping 54. As shown in FIG. 12, piping 58 extends out of aside wall 268 b of dust collector flange 268 so as to provide an airexit for (1) depressurizing the transfer pot 218, and (2) equalizing thepressure between the transfer pot 218 and the dust collector 216.

As shown in FIG. 12, the flexible section 268 a is subject to pressureduring pressurization of the transfer pot 218. Consequently, thematerial used to form flexible section 268 a, and connections theretoare constructed so as to withstand pressures used within transfer pot218 for transfer of one or more catalysts and/or additives from thetransfer pot 218 to the fluidized catalytic cracking unit (not shown)via outlet piping 54.

As shown in FIG. 12, the dust collector 216 utilizes a manifold 74 andsingle pipe guide 40 as described above with reference to FIG. 8. Inthis exemplary embodiment, single pipe guide 40 is in fluidcommunication with multiple hoses 38 via manifold 74, wherein each hose38 is in fluid communication with a corresponding storage bin 37.Catalyst and/or additive is drawn into the internal volume 26 of dustcollector 216 by way of pipe guide 40, and is discharged proximatescreen 24 as shown in FIG. 12. Similar to loading system 10 shown inFIG. 1 and loading system 110 shown in FIG. 11, alternative manifold andguide pipes illustrated in FIGS. 9-11 may be used within loading system211 shown in FIG. 12.

As with loading system 100, loading system 210 further comprises legs120, which support the weight of the dust collector 216 above thetransfer pot 218. As discussed above, in alternative embodiments (notshown), the weight of the dust collector 216 may be supported by wallstructure of the cabinet 19 (see, the cabinet 19 in FIGS. 2-4).

Loading system 210 operates in a manner as described above in referenceto loading system 10 and loading system 100, except that the pluralityof load cells 56 only weigh the transfer pot 218, its contents (i.e.,the catalyst and/or additive), and a minimum number of componentsattached to the transfer pot 218 (i.e., a portion of piping 54, transferpot flange 368, and legs 20 as shown in FIG. 12). In this embodiment,the plurality of load cells 56 do not weigh the dust collector 160, thecontents of the dust collector 160 (e.g., filter 32, pipe guides 40,particles that do not pass thru screen 24), components attached to thedust collector 160 (e.g., hoses 35 and 38, valves 42, manifold 74, dustcollector flange 268, portions of piping 46 and 58, etc.) and componentsattached to or contained within dust collector flange 268 (e.g., portionof hoses 46 and 58, and plug 45).

As noted above, flexible sections, such as flexible sections 46 a, 54 a,58 a, 168 a and 268 a, enable components positioned away from the loadcells 56 relative to a given flexible section (e.g., components such asvalve 48 and moisture trap 49 in loading system 10; components such asvalve 48, moisture trap 49 and dust collector 160 in loading system 100;and components such as dust collector flange 268 and dust collector 216in loading system 210) to contribute a negligible amount, if any, to theweight readings of the plurality of load cells 56. It should be notedthat each flexible section may comprise any material and have anyconfiguration that (1) enables components positioned away from theplurality of load cells 56 relative to a given flexible section tocontribute a negligible amount, if any, to the weight readings of theplurality of load cells 56, and (2) withstands any pressure exerted on agiven flexible section within a given loading system.

One exemplary vertically-extending flexible section that may be used,for example, as flexible section 58 a, 168 a and/or 268 a, is shown inFIG. 13. As shown in FIG. 13, exemplary vertically-extending flexiblesection 222 a connects (i) dust collector flange 268 and one or morecomponents 224 positioned above flexible section 222 a and dustcollector flange 268 to (ii) transfer pot flange 368 and one or morecomponents 225 positioned below flexible section 222 a. For example, inloading system 210, the one or more components 224 positioned aboveflexible section 222 a (namely, above dust collector flange 268 andflexible section 268 a shown in FIG. 12) include dust collector 216,piping 58, piping 46, and all other components positioned above piping58 and piping 46 as shown in FIG. 12, while the one or more components225 positioned below transfer pot flange 368 and flexible section 222 a(namely, below transfer pot flange 368 and flexible section 268 a shownin FIG. 12) include the transfer pot 218, legs 20 and a portion ofpiping 54 exiting transfer pot 218 as shown in FIG. 12.

As shown in FIG. 13, exemplary vertically-extending flexible section 222a comprises an expandable section 223 comprising overlapping portions230 a, 230 b and 230 c of side wall 230 having a crease/indentation 230a therein. As a lower portion of flexible section 222 a and components225, collectively designated 228, move up or down in direction A, anupper portion of flexible section 222 a and components 224, collectivelydesignated 226, remain stationary. At the same time, as a lower portionof flexible section 222 a and components 225, collectively designated228, move up or down in direction A, expandable section 230 a eitherslightly expands (i.e., during downward movement) or slightly contracts(i.e., during upward movement).

Although expandable section 223 of exemplary vertically-extendingflexible section 222 a is shown as a crease/indentation 230 a, it shouldbe understood that any configuration may be used within flexible section222 a as long as flexible section 222 a the configuration (1) enablesthe transfer pot and its contents to be weighed with little or no weightcontribution from the dust collector as discussed above, and (2)withstands the pressure exerted on the loading system during operation.

As shown in FIG. 13, exemplary vertically-extending flexible section 222a may be attached to ends of (i) dust collector flange 268 and (ii)transfer pot flange 368 via exemplary clamping members 388 (e.g., ametal band having screw threads therein) and exemplary tighteningmembers 389 (e.g., a screw). It should be understood that flexiblesections disclosed herein (e.g., exemplary vertically-extending flexiblesection 222 a) may be attached to ends of (i) dust collector flange 268and (ii) transfer pot flange 368 via any type of connector (e.g.,chemicals (e.g., adhesives), mechanical connectors such as shown in FIG.13, and electrical/magnetic connectors) as long as the connectionwithstands any pressure exerted thereon.

Suitable materials for forming any of the above-described flexiblesections include, but are not limited to, an elastomeric material,rubber, nylon, etc. In one exemplary embodiment, flexible sections, suchas flexible section 168 a and 268 a comprise a vinyl sleeve with orwithout sleeve reinforcement (e.g., a fiber-reinforced vinyl sleeve).

As discussed above, the systems of the present invention enableefficient injection of one or more catalysts and/or additives into afluidized catalytic cracking unit. As described illustratively in FIGS.11-13, the systems of the present invention may comprise one or more ofthe following components and/or component features:

a dust collector in fluid communication with at least one storage binholding one or more catalysts and/or additives;

a vacuum producer in fluid communication with the dust collector so thatthe vacuum producer generates a vacuum within the dust collector thatdraws the one or more catalysts and/or additives into the dustcollector;

a transfer pot in fluid communication with the dust collector forreceiving the one or more catalysts and/or additives from the dustcollector, the transfer pot being in fluid communication with thefluidized catalytic cracking unit;

a plurality of load cells for measuring the transfer pot and the one ormore catalysts and/or additives positioned within the transfer pot,wherein the weight measured by the plurality of load cells containseither (i) a minimal weight contribution provided by the dust collectoror (ii) no weight contribution provided by the dust collector;

a cabinet for housing the dust collector and the transfer pot;

one set of a plurality of legs, wherein only the transfer pot is mountedon the plurality of legs, and each of the legs is secured to a commonplate, the plate is mounted on the plurality of load cells, and theplurality of load cells are optionally mounted on a base of the cabinet;

two separate sets of a plurality of legs, wherein a first set of aplurality of legs supports the dust collector and a second set of aplurality of legs supports the transfer pot, and each of the legs withinthe second set of legs is secured to a common plate, the plate ismounted on the plurality of load cells, and the plurality of load cellsare optionally mounted on a base of the cabinet;

the dust collector and the transfer pot are separate and separatablefrom one another and each comprises separate respective sidewalls;

at least one flexible section positioned between and in fluidcommunication with the dust collector and the transfer pot;

at least one flexible section comprising a vertically-extending flexiblesection; and

two vertically-extending flexible sections positioned between and influid communication with the dust collector and the transfer pot.

The present invention is also directed to processes such as processesfor introducing one or more catalysts and/or additives into a fluidizedcatalytic cracking unit. The processes may comprise one or more processsteps and/or process features:

storing at least one or more catalysts and/or additives at a firstlocation;

generating a vacuum within a loading unit comprising a dust collector influid communication with and separatable from a transfer pot;

drawing the one or more catalysts and/or additives from one or morestorage bins and into the dust collector of the loading unit in responseto the vacuum;

determining a weight of the one or more catalysts and/or additivespositioned in the transfer pot of the loading unit, wherein thedetermining step comprises weighing the transfer pot and the one or morecatalysts and/or additives positioned in the transfer pot so as toobtain a transfer pot/contents weight, wherein the transfer pot/contentsweight contains either (i) a minimal weight contribution provided by thedust collector or (ii) no weight contribution provided by the dustcollector;

monitoring a weight of the one or more catalysts and/or additives drawninto the loading unit (i.e., the transfer pot) and stopping generationof the vacuum when the weight reaches a predetermined value;

pressurizing the transfer pot of the loading unit;

injecting the one or more catalysts and/or additives into the fluidizedcatalytic cracking unit in response to reaching a threshold pressurewithin the transfer pot of the loading unit.

The foregoing description is provided for the purpose of explanation andis not to be construed as limiting the invention. While the inventionhas been described with reference to preferred embodiments or preferredmethods, it is understood that the words which have been used herein arewords of description and illustration, rather than words of limitation.Furthermore, although the invention has been described herein withreference to particular structure, methods, and embodiments, theinvention is not intended to be limited to the particulars disclosedherein, as the invention extends to all structures, methods and usesthat are within the scope of the appended claims. Those skilled in therelevant art, having the benefit of the teachings of this specification,may affect numerous modifications to the invention as described herein,and changes may be made without departing from the scope and spirit ofthe invention as defined by the appended claims.

Parts List

-   Loading systems 10, 100 and 210-   Systems 11, 110 and 210 for storing and loading catalyst and/or    additives-   Loading units 14, 140 and 214-   Dust collectors 16, 160 and 216-   Upper portion 16 a (of dust collector 16, 160 or 216)-   Lower portion 16 b (of dust collector 16, 160 or 216)-   Sidewall 17 (of dust collector 16, 160 or 216)-   Transfer pots 18, 180 and 218-   Cabinet 19-   Base 19 a (of cabinet 19)-   Legs 20 (on loading unit 14, 140 or 214)-   Legs 120 (on loading unit 140 or 214)-   Opening 23 (in lower portion 16 b)-   Screen 24-   Cover 25-   Internal volume 26 (within dust collector 16, 160 or 216)-   Vacuum producer 30-   Filter 32-   Hatch 33 (in dust collector 16, 160 or 216)-   Brackets 34-   Hose 35-   Valve 36-   Actuator 36 a (of valve 36)-   Storage bins 37-   Hoses 38-   Arrows 39-   Pipe guides 40-   Valve 42-   Actuator 42 a (of valve 42)-   Valve 43-   Seats 44 and 144-   Plug 45 (of valve 43)-   Piping 46-   Flexible section 46 a (of piping 46)-   Valve 48-   Actuator 48 a (of valve 48)-   Volume chamber and moisture trap 49-   Internal volume 50 (within transfer pot 18, 180 or 218)-   Sidewall 51 (of transfer pot 18, 180 or 218)-   Opening 53 (in lower portion 18 a of transfer pot 18, 180 or 218)-   Piping 54-   Flexible section 54 a (of piping 54)-   Valve 55-   Actuator 55 a (of valve 55)-   Load cells 56-   Plate 57-   Piping 58-   Flexible section 58 a (of piping 58)-   Valve 59-   Controller 60-   Brackets 61-   Jack assemblies 62-   Shafts 62 a (of jack assemblies 62)-   Nuts 62 b-   Control panel 64 (of controller 60)-   Arrows 65-   First pressure transducer 68-   Second pressure transducer 70-   Third pressure transducer 72-   Manifold 74-   Manifold 100-   Pipe guides 102-   Discharge pipe guide 104-   Pipe guides 110-   Dust collector flange 168 and 268-   Transfer pot flange 368-   Flexible section 168 a (connecting dust collector flange 168 to    transfer pot flange 368)-   Flexible section 268 a (connecting dust collector flange 268 to    transfer pot flange 368)-   Flexible section 222 a-   Clamping members 388-   Tightening members 389-   One or more components 224 (positioned above flexible section 222 a)-   One or more components 225 (positioned below flexible section 222 a)-   Expandable section 223 (of flexible section 222 a)-   Side wall 230 (of flexible section 222 a)-   Indentations 230 a (of flexible section 222 a)-   Lower portion of flexible section 222 a and components 225,    collectively designated 228-   Upper portion of flexible section 222 a and components 224,    collectively designated 226-   Direction A

What is claimed is:
 1. A system for injecting catalyst and/or additivesinto a fluidized catalytic cracking unit, comprising: a dust collectoradapted to be in fluid communication with at least one storage binholding one of the catalyst and/or additives; a vacuum producer in fluidcommunication with the dust collector so that the vacuum producergenerates a vacuum within the dust collector that draws the one of thecatalyst and/or additives into the dust collector; a transfer pot whichis selectively in fluid communication with the dust collector forreceiving the one of the catalyst and/or additives from the dustcollector, the transfer pot adapted to be in fluid communication withthe fluidized catalytic cracking unit and a source of pressurized air sothat the one of the catalyst and/or additives can be transferred to thefluidized catalytic cracking unit in response to a pressure differentialbetween the transfer pot and the fluidized catalytic cracking unit; atleast one flexible section positioned between and in fluid communicationwith said dust collector and said transfer pot; a first valve forisolating said dust collector from said transfer pot, disposed betweensaid dust collector and said transfer pot, such that when said valve isopened, said dust collector and said transfer pot are in fluidcommunication with each other and such that when said valve is closed,said dust collector and said transfer pot are not in fluid communicationwith each other; and a controller electrically coupled to an actuator ofsaid first valve and to an actuator of said vacuum producer forcontrolling operation of said first valve and said actuator of saidvacuum producer, wherein said controller is programmed such that saidfirst valve is open while said vacuum producer generates said vacuumwithin the dust collector.
 2. The system of claim 1, wherein each ofsaid at least one flexible section comprises a vertically-extendingflexible section.
 3. The system of claim 2, wherein said systemcomprises a single flexible section positioned between and in fluidcommunication with said dust collector and said transfer pot.
 4. Thesystem of claim 1, wherein the source of pressurized air is connected tosaid transfer pot via piping that extends through a sidewall of saidtransfer pot.
 5. The system of claim 1, wherein the source ofpressurized air is connected to said transfer pot via piping thatextends through a sidewall of piping positioned above said at least oneflexible section.
 6. The system of claim 1, further comprising aplurality of load cells for measuring a weight of the transfer pot, andthe one of the catalyst and/or additives positioned within the transferpot.
 7. The system of claim 6, wherein the weight measured by saidplurality of load cells contains either (i) a minimal weightcontribution provided by said dust collector or (ii) no weightcontribution provided by said dust collector.
 8. The system of claim 1,wherein: the dust collector comprises a substantially cylindrical upperportion and an adjoining, substantially conical lower portion; and thetransfer pot comprises a substantially cylindrical upper portionseparated from the lower portion of the dust collector by said at leastone flexible section, and a substantially conical lower portionadjoining the upper portion of the transfer pot.
 9. The system of claim8, wherein the lower portion of the dust collector has an opening formedtherein for permitting the one of the catalyst and/or additives to flowfrom the dust collector to the transfer pot.
 10. The system of claim 9,wherein the first valve has a plug movable between an upper and a lowerposition in response to impingement of the pressurized air thereon. 11.The system of claim 9, wherein the upper portion of the transfer pot hasan opening formed therein for permitting the one of the catalyst and/oradditives to flow into the transfer pot, the first valve being disposedin the transfer pot covering the opening in the upper portion of thetransfer pot on a selective basis, the first valve having a plug movablebetween an upper and a lower position in response to impingement of thepressurized air thereon.
 12. The system of claim 8, wherein the lowerportion of the transfer pot has an opening formed therein for permittingthe one of the catalyst and/or additives to flow from the transfer potto the fluidized catalytic cracking unit.
 13. The system of claim 6,where the vacuum producer is in fluid communication with the source ofpressurized air, and the system further comprises: a second valve forisolating the vacuum producer from the source of pressurized air on aselective basis; a third valve for isolating the transfer pot from thesource of pressurized air on a selective basis; a fourth valve forisolating the transfer pot from the fluidized catalytic cracking unit ona selective basis; and a fifth valve for isolating the dust collectorfrom at least one storage bin on a selective basis; wherein saidcontroller is electrically coupled to the load cells and respectiveactuators of the second, third, fourth and fifth valves for controllingthe operation of the second, third, fourth and fifth valves.
 14. Thesystem of claim 13, wherein the controller: generates a first controlinput to cause the second valve to open; generates a second and a thirdcontrol input that cause the respective second and the fifth valves toclose after a predetermined amount of the one of the catalyst and/oradditives has been drawn into the dust collector; generates a fourthcontrol input that causes the third valve to open to pressurize thetransfer pot; generates a fifth control input that causes the thirdvalve to close after a pressure differential between the transfer potand a regenerator of the fluidized catalytic cracking unit reaches apredetermined value; and generates a sixth control input that causes thefourth valve to open.
 15. The system of claim 1, wherein the systemfurther comprises at least two storage bins holding the one or morecatalysts and/or additives, the dust collector adapted to be in fluidcommunication with said at least two one storage bins via valves.
 16. Asystem for injecting one or more catalysts and/or additives into afluidized catalytic cracking unit comprising: a dust collector adaptedto be in fluid communication with at least one storage bin holding theone or more catalysts and/or additives; a transfer pot which isselectively in fluid communication with the dust collector for receivingthe one or more catalysts and/or additives from the dust collector, thetransfer pot adapted to be in fluid communication with the fluidizedcatalytic cracking unit and a source of pressurized air so that the oneor more catalysts and/or additives can be transferred to the fluidizedcatalytic cracking unit in response to a pressure differential betweenthe transfer pot and the fluidized catalytic cracking unit; at least oneflexible section positioned between and in fluid communication with saiddust collector and said transfer pot; a plurality of load cellsoperatively adapted and positioned to weigh the transfer pot and the oneor more catalysts and/or additives; a vacuum producer in fluidcommunication with the dust collector so that the vacuum producergenerates a vacuum within the dust collector that draws the one or morecatalysts and/or additives into the dust collector; a first valve forisolating said dust collector from said transfer pot, disposed betweensaid dust collector and said transfer pot, such that when said valve isopened, said dust collector and said transfer pot are in fluidcommunication with each other and such that when said valve is closed,said dust collector and said transfer pot are not in fluid communicationwith each other; and a controller electrically coupled to an actuator ofsaid first valve and to an actuator of said vacuum producer forcontrolling operation of said first valve and said actuator of saidvacuum producer, wherein said controller is programmed such that saidfirst valve is open while said vacuum producer generates said vacuumwithin the dust collector, and wherein said at least one flexiblesection enables a weight reading of said plurality of load cells tocontain either (i) a minimal weight contribution provided by said dustcollector or (ii) no weight contribution provided by said dustcollector.
 17. The system of claim 16, wherein said dust collectorcomprises a plurality of legs so as to support said dust collector abovesaid transfer pot.
 18. The system of claim 16, wherein the systemfurther comprises at least two storage bins holding the one or morecatalysts and/or additives, the dust collector adapted to be in fluidcommunication with said at least two one storage bins via valves.